Polymers

Polymers: big molecules made from repeating units.

Polymers (plastics) have a zillion uses.

Question: Why are polymers so useful and versatile? 

Answers:

  • Many types of polymers exist
  • Each type has some useful properties, such as mechanical strength, flexibility, electrical insulation, chemical resistance, or optical clarity.
  • Polymer recipes can be customized to get just the right mix of properties for almost any product
  • Polymers can be mass produced to make products less expensive than things made from metals, ceramics, or organic materials such as wood
  • Polymers are generally lightweight and strong for their weight.
Example Polymer: Polypropylene
393px-Resin-identification-code-5-PP.svg

Polypropylene is a type of plastic. Lots of products are made from polypropylene. Here are a few examples:

PPropePPcontainersPPcovers

Polypropylene is made by combining lots of propylene molecules.(propylene is the same thing as propene)

\chemname{\chemfig{[,.6]H-C(-[6]H)=C(-[6]H)-C(-[6]H)(-[2]H)-H}}{propylene}

\chemname{\chemfig{[,.6]CH_2=CH-CH_3}}{propylene}

Those structures both show the same molecule, but a bent version of polypropylene can help to show how lots of these molecules can chain together:

\setchemrel{}{}{.8} \chemfig{[,.6]CH(-[6]CH_3)=CH_2} \chemrel{->} \chemfig{[,.6]CH(-[4])(-[6]CH_3)-CH_2(-)}

The polymer version loses the double bonds and connects to other molecules. Here is a section of polypropylene molecule made of four units:

\definesubmol{a}{-[,.4]CH(-[6]CH_3)-CH_2-[,.2]} ... \chemfig{[,.6]!a!a!a!a-[,.2]} ...

The dots are meant to indicate that the pattern could go on forever in both directions. A typical polypropylene molecule is thousands of units long.

Important Polymers in Consumer Products:

Polyethylene (HDPE” and “LDPE”): simplest type of plastic – milk jugs, yogurt containers, shopping bags, and a zillion other products are made of this.

Polycarbonate: bullet resistant “glass,” eyeglass lenses

Polyvinyl Acetate (PVC): PVC pipe, shoes

Polyethylene Terephthalate (PET): pop bottles

Polystyrene (PS): Solo cups, styrofoam

Important Polymers in Living Things:

DNA is a polymer made of phosphate, ribose (a sugar) and nucleic acids.

Starch is a polymer made of sugars.

Protein is a polymer made of amino acids.